Beyond-silicon technology demands ultra-high-performance field-effect transistors (FETs). Transition metal dichalcogenides (TMDs) provide an ideal material platform, but the device performances such as contact resistance, on/off ratio, and mobility are often limited by the presence of interfacial residues caused by transfer procedures. We show an ideal residue-free transfer approach using polypropylene carbonate (PPC) with a negligible residue for monolayer MoS2. By incorporating bismuth semimetal contact with atomically clean monolayer MoS2-FET on h-BN substrate, we obtain an ultralow Ohmic contact resistance approaching the quantum limit and a record-high on/off ratio of ~1011 at 15 K. Such an ultraclean fabrication approach could be the ideal platform for high-performance electrical devices using large-area semiconducting TMDs.
A revolution in technology is on the horizon, and it's poised to change the devices that we use. Under the distinguished leadership of Professor LEE Young Hee, a team of visionary researchers from the Center for Integrated Nanostructure Physics within the Institute for Basic Science (IBS), South Korea, has unveiled a new discovery that can greatly improve the fabrication of field-effect transistors (FET).
A high-performance field-effect transistor (FET) is an essential building block for next-generation beyond-silicon-based semiconductor technologies. Current 3-dimensional silicon technology suffers from degradation of FET performances when the device is miniaturized past sub-3-nm scales. To overcome this limit, researchers have studied one-atom thick (~0.7 nm) two-dimensional (2D) transition metal dichalcogenides (TMDs) as an ideal FET platform over the last decade. Nevertheless, their practical applications are limited due to the inability to demonstrate integration at the wafer-scale.
A major problem is the residues that occur during fabrication. Traditionally, polymethyl methacrylate (PMMA) is used as a supporting holder for device transfer. This material is notorious for leaving insulating residues on TMD surfaces, which often generates mechanical damage to the fragile TMD sheet during transfer. As an alternative to PMMA, several other polymers such as polydimethylsiloxane (PDMS), polyvinyl alcohol (PVA), polystyrene (PS), polycarbonate (PC), ethylene vinyl acetate (EVA), polyvinylpyrrolidone (PVP) and organic molecules including paraffin, cellulose acetate, naphthalene have all been proposed as a supporting holder. Nevertheless, residues and mechanical damages are inevitably introduced during transfer, which leads to degradation of FET performances.
The IBS researchers addressed this problem and have made an intriguing breakthrough by successfully harnessing polypropylene carbonate (PPC) for residue-free wet transfer. Using PPC not only eliminated residue but also allowed for the production of wafer-scale TMD using chemical vapor deposition. Previous attempts at manufacturing large-scale TMDs often resulted in wrinkles, which occur during the transfer process. The weak binding affinity between the PPC and the TMD not only eliminated residues but wrinkles as well.
Mr. Ashok MONDAL, the first author of the study said, "The PPC transfer method we chose enables us to fabricate centimeter-scale TMDs. Previously, TMD was limited to being produced using a stamping method, which generates flakes that are only 30-40 μm in size."
The researchers built a FET device using a semimetal Bi contact electrode with a monolayer of MoS2, which was transferred by the PPC method. Less than 0.08% of PPC residue was found to remain on the MoS2 layer. Thanks to the lack of interfacial residues, the device was found to have an ohmic contact resistance of RC ~78 Ω-µm, which is close to the quantum limit. An ultrahigh current on/off ratio of ~1011 at 15 K and a high on-current of ~1.4 mA/µm were also achieved using the h-BN substrate.
This finding was the first in the world that demonstrated wafer-scale production and transfer of CVD-grown TMD. The state-of-the-art FET device produced in this way was found to have electrical properties that far exceed that of previously reported values. It is believed that this technology can be easily implemented using the currently available integrated circuit manufacturing technology.
Dr. Chandan BISWAS, the co-corresponding author of the study said, "It is hoped that our success in the residue-free PPC transfer technique will encourage other researchers to develop further improvements in various TMD devices in the future."