Posted in | News | Plastics and Polymers | Materials Testing | Energy | Fuel Cell | Petrochemicals | Materials Analysis | Electronics | Automotive Materials

Sandia Develop New Polymer Electrolyte For Fuel Cells

May 7 2004

A new type of polymer electrolyte membrane (PEM) is being developed by researchers at the Department of Energy’s Sandia National Laboratories to help bring the goal of a micro fuel cell closer to realization using diverse fuels like glucose, methanol, and hydrogen.

This Sandia Polymer Electrolyte Alternative (SPEA) could help fulfill the need for new, uninterrupted autonomous power sources for sensors, communications, microelectronics, healthcare applications, and transportation.

The membrane research is one part of a three-year internally funded Bio-Micro Fuel Cell Grand Challenge led by Chris Apblett, Sandia principal investigator, and Kent Schubert, Sandia project manager.

Recently the membrane research team headed by Sandia researcher Chris Cornelius demonstrated that the new SPEA could operate as high as 140 degrees C and produce a peak power of 1.1 watts per square centimeter at 2 amps per square centimeter at 80 degrees C. Under identical operating conditions, the SPEA material can deliver higher power outputs with methanol and hydrogen than Nafion. Nafion is recognized as the state-of-art PEM material for fuel cells.

Because the SPEA material can operate at elevated temperatures, it enables several key benefits that Nafion cannot provide. These advances include smaller fuel cell stacks because of better heat rejection, enhanced water management, and significant resistance to carbon monoxide poisoning. These performance properties suggest that the SPEA material may be a potential alternative to Nafion.

Cornelius notes that a higher temperature PEM material is one of the goals of the DOE’s Hydrogen, Fuel Cells, and Infrastructure Technologies Program. One milestone is to develop by 2005 polymer electrolyte membranes for automotive applications that operate at 120 degrees C for 2,000 hours with low membrane interfacial resistance.

Of the new SPEA material that Cornelius and Sandia researcher Cy Fujimoto developed, Cornelius says, “Validation of this material as a Nafion alternative would be a significant achievement, an accomplishment we strongly desire.”

Related Stories

A polymer electrolyte membrane is a critical component of a working fuel cell. Its function is to conduct protons efficiently and possess low fuel crossover properties. It must also be robust enough to be assembled into a fuel cell stack and have long life.

In developing the SPEA material, the team looked at the success and limitations of other PEM alternatives in order to develop a set of characteristics for their model material.

“At the beginning of this project we were considering several polymer families for a PEM alternative, including a family of polyphenylenes,” Cornelius says. “When the physical properties of one of the polyphenylenes being considered as a polymer electrolyte was improved and integrated into a working fuel cell, we happily discovered that it works extremely well compared to Nafion.”

Cornelius says that the SPEA material he and Fujimoto are developing “may be an enabling material that could have an impact on the fuel cell community and help Sandia become recognized as a fuel cell research organization.”

“We have already completed initial material validation studies of our SPEA with the help of our battery group and Los Alamos National Laboratory,” he says.

The next steps, Cornelius says, are to reduce the internal resistance in the fuel cell membrane electrode assembly, optimize catalyst and ionomer composition, improve the properties of the SPEA material, conduct life cycle testing in a fuel cell environment, and assess the potential value for large-scale commercialization of the polymer electrolyte.

Understanding the material’s capabilities and limitations are necessary steps in order to potentially improve the physical properties of SPEA material.

“We see this SPEA material as having the potential of being integrated into fuel cells ranging from microwatts to kilowatts,” he says. “Such a broad power range means that this Sandia Polymer Electrolyte Alternative could be used in a fuel cell to power everything from sensors, cell phones, laptops, and automobiles.”

For more information on fuel cells, click here.

Tell Us What You Think

Do you have a review, update or anything you would like to add to this news story?

Leave your feedback
(Logout)
Your comment type
Submit

Sponsored Content

Editorial Highlights

The Current State of the Global Semiconductor Market

The Current State of the Global Semiconductor Market

The global semiconductor market has entered an exciting period. Demand for chip technology is both driving the industry as well as hindering it, with current chip shortages predicted to last for some time. Current trends will likely shape the future of the industry, which is set to continue to show

How are Graphene Batteries Made?

How are Graphene Batteries Made?

The primary distinction between graphene-based batteries and solid-state batteries lies in the composition of either electrode. Although the cathode is commonly changed, carbon allotropes can also be employed in fabricating anodes.

Newsletters you may be interested in

See all Newsletters »

Terms

While we only use edited and approved content for Azthena answers, it may on occasions provide incorrect responses. Please confirm any data provided with the related suppliers or authors. We do not provide medical advice, if you search for medical information you must always consult a medical professional before acting on any information provided.

Your questions, but not your email details will be shared with OpenAI and retained for 30 days in accordance with their privacy principles.

Please do not ask questions that use sensitive or confidential information.

Read the full Terms & Conditions.

Provide Feedback