Researchers Discover Metallic Gold Nanoparticles in Common Minerals

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Researchers are exploring mineral deposits containing locked resources of gold in refractory ores using Curtin University’s new Geoscience Atom Probe Facility.

Curtin WA School of Mines Research Associate in Applied Geology, Dr Denis Fougerouse, and fellow researchers have discovered metallic gold nanoparticles measuring just a few nanometers in diameter inside arsenopyrite – a common mineral found in Australian mines.

Dr Fougerouse stated that the research was considered to be unique, and the discovery challenges the comprehension of nanoparticle formation and allowed the team to determine the key controls on gold integration in sulfides.

The application of atom probe microscopy in geosciences is relatively new. The technique is based on field-evaporation of atoms from tiny, needle-shaped specimens to provide three dimensional subnanometre scale information of the position and type of individual atoms in the specimen in the mineral.

Dr Denis Fougerouse, Research Associate, Curtin University

“Typically, the amount of material analysed is really, really small – a single grain of salt is over a billion times larger than a typical analysis.” Dr Fougerouse explained large amounts of resources of these nanoparticles can be found embedded within gold-bearing arsenopyrite, an iron arsenic sulfide, which are present in mines across the world.

“Arsenopyrite is a very common mineral found in Australian and other mines, and although not every arsenopyrite contains gold, it is common to find gold locked inside this mineral,” he said. “Our results show that gold can be hosted either as nanoparticles or as individual atoms in different parts of the crystal structure, and the different types of gold yield important information about the controls on gold deposition as the ore body forms.”

Dr Fougerouse explained this study demonstrated the capability of atom probe microscopy in geosciences.

Our research shows the Geoscience Atom Probe has potential to characterise gold deposition processes at the atomic level. In turn this could help unlock hidden gold resources in known deposits, and will enhance gold recovery.

Dr Denis Fougerouse, Research Associate, Curtin University

“Nanogeoscience is a new, but rapidly growing research field. Through this research and use of the Geoscience Atom Probe, we can show that tiny observations can yield big results that have potential economic importance.”

The research paper titled, Nanoscale gold clusters in arsenopyrite controlled by growth rate not concentration: Evidence from atom probe microscopy, was published in American Mineralogist. The Geosciences Atom Probe is housed in the John de Laeter Centre, Curtin University and forms part of the National Resource Science Precinct’s (NRSP) Advanced Resource Characterisation Facility (ARCF), a joint project between CSIRO, Curtin University and The University of Western Australia, with funding support from the Science and Innovation Endowment Fund.

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